Relative Volatility of Binary Mixture in High Vacuum Distillation

Simple batch distillation of a binary mixture

A simple experiment such as the batch distillation of an ethanol–water binary mixture can be performed in a 3-h laboratory session using a very rudimentary apparatus consisting of a still pot and two thermocouples. Yet, the results can lead to very interesting insights to distillation and chemical engineering thermodynamics. The present article describes how one can exploit this simple laborato...

Relative volatilities of ionic liquids by vacuum distillation of mixtures.

The relative volatilities of a variety of common ionic liquids have been determined for the first time. Equimolar mixtures of ionic liquids were vacuum-distilled in a glass sublimation apparatus at approximately 473 K. The composition of the initial distillate, determined by NMR spectroscopy, was used to establish the relative volatility of each ionic liquid in the mixture. The effect of alkyl ...

Multistage vacuum membrane distillation (MSVMD) systems for high salinity applications

Multistage membrane distillation (MD) systems can have significantly higher efficiencies than their single stage counterparts. However, multistage MD system design has received limited attention. In this paper, the performance of a multistage vacuum membrane distillation (MSVMD) which is thermodynamically similar to a multi-stage flash distillation (MSF) is evaluated for desalination, brine con...

Distillation of a Complex Mixture. Part I: High Pressure Distillation Column Analysis: Modeling and Simulation

In this analysis, based on the bubble point method, a physical model was established clarifying the interactions (mass and heat) between the species present in the streams in circulation in the column. In order to identify the externally controlled operating parameters, the degree of freedom of the column was determined by using Gibbs phase rule. The mathematical model converted to Fortran code...

Vacuum Booster for Distillation Process